Peace is a gracious gift from God, but it is not presented in Scripture as a reliable method for discerning His will. Often times people use this method to determine specifics from God (where to live, what job to take, and more), but God has already revealed His will in His Word—calling us to obedience and holiness (1 Thessalonians 4:3). He renews our minds through Scripture (Romans 12:2; 2 Timothy 3:16–17) and gives us what we need to walk in wisdom rather than trusting our own hearts (Jeremiah 17:9; Proverbs 14:12). While God promises peace for those who trust in Him, decision-making is rooted in trusting the Lord, not leaning on our own understanding (Proverbs 3:5–6). As we obey what He has clearly revealed, we can move forward confidently, knowing He sovereignly directs our steps (Proverbs 16:9).
There are many ways both Christians and non-Christians alike try to discern what they are to do. It can range from looking for signs in nature to observing coincidences to looking for “open doors.” Striving for a feeling of peace about a specific decision can be an activity similar to those others. Rather than being a biblical practice, it can have more in common with new age or other subjective ways people try to figure out what they should do.
Fortunately, God has already given us everything we need to live a godly life (2 Timothy 3:16–17). There is nothing else we need to please Him. We have His will: it’s in the Bible! Our primary way of determining what God wants us to do is by comparing what we want to do through the lens of Scripture. If it does not obviously contradict God's Word, then we are free to move forward. That said, while we plan our steps, God directs our paths (Proverbs 16:9). Believers can ultimately rest in the fact that as long as we are obeying God, He will place us right where He wants us.
Still, we should not completely dismiss our feelings. While “peace” is subjective, it can still be like a gauge we should acknowledge. For example, a lack of peace might be your conscience warning you that you are entering an area of sin. Listen to it. But, even there, be careful. You need to confirm everything by Scripture. In short, your feelings of peace or a lack of peace may be right, but they also might be wrong. This is why God's Word, not our feelings, must be the final authority of all we do.